Table 5:

Purity of normal and deuterated isotopologues of additional odorants

h-Acetophenone (Fluka analytical)d3-Acetophenone
Peak
#
Ret time
(min)
TypeWidth
(min)
Area
(pA*s)
Height
(pA)
Area
%
Peak
#
Ret time
(min)
TypeWidth
(min)
Area
(pA*s)
Height
(pA)
Area
%
18.634VV0.05321.754455.22483e-10.0204419.212BB0.04596.59789e-12.27296e-10.00659
29.091VB0.03791.110034.33768e-10.01293210.060BB0.04329.676173.623140.09659
39.499BB0.04091.464425.19445e-10.01706310.384BB0.04439.542383.443150.09526
410.206VB0.04519.35422e-13.11201e-10.01090410.844BV0.07639988.407231933.7159499.71190
510.909VV0.06058552.973631899.8768399.66466511.217VB0.04007.89751e-13.28895e-10.00788
611.145VV0.03512.059788.85598e-10.02400611.785BB0.06821.586335.11016e-10.01584
711.272VV0.03022.009641.057440.02342712.807BB0.03345.713623.113830.05704
811.337VV0.02551.288597.71482e-10.01502813.684BB0.03698.92039e-14.17685e-10.00891
911.391VB0.03001.066455.65312e-10.01243
1011.826BB0.02967.876614.262060.09178
1112.824BB0.02673.461711.948070.04034
1212.967BV0.03187.98368e-13.91961e-10.00930
1313.008VB0.02796.91700e-13.68989e-10.00806
1414.378BB0.02654.260802.420680.04965
d5-Acetophenoned8-Acetophenone (lot G466P29)
Peak
#
Ret time
(min)
TypeWidth
(min)
Area
(pA*s)
Height
(pA)
Area
%
Peak
#
Ret time
(min)
TypeWidth
(min)
Area
(pA*s)
Height
(pA)
Area
%
110.866BB0.09339092.358401730.3128799.9891918.259BB0.03671.775878.40201e-10.01898
211.796BB0.03579.82952e-14.83287e-10.0108128.850BB0.03281.342826.81408e-10.01435
310.820BB0.09339347.320311778.2832099.90145
411.766BB0.03791.431556.45780e-10.01530
512.484BB0.03792.748611.238740.02938
613.712BB0.03911.489176.42145e-10.01592
716.677BB0.03134.32479e-12.30103e-10.00462
h-Ethanold6-Ethanol
Peak
#
Ret time
(min)
TypeWidth
(min)
Area
(pA*s)
Height
(pA)
Area
%
Peak
#
Ret time
(min)
TypeWidth
(min)
Area
(pA*s)
Height
(pA)
Area
%
12.418BB S0.02054076.575933284.198731.000e212.387BB0.03604830.660642824.425051.000e2
h-1-Pentanold11-1-Pentanol
Peak
#
Ret time
(min)
TypeWidth
(min)
Area
(pA*s)
Height
(pA)
Area
%
Peak
#
Ret time
(min)
TypeWidth
(min)
Area
(pA*s)
Height
(pA)
Area
%
12.711BB0.02316.06239e-14.13028e-10.0085313.443BB0.042111.470776.048650.15594
24.421BB0.03631.786957.93818e-10.0251523.984BB0.038124.5006312.942810.33307
35.023BB0.06187100.833501662.5285699.9444534.528BB0.07927319.982911443.7783299.51099
45.750BB0.02311.553541.059580.02187
h-1-Octanold17-1-octanol
Peak
#
Ret time
(min)
TypeWidth
(min)
Area
(pA*s)
Height
(pA)
Area
%
Peak
#
Ret time
(min)
TypeWidth
(min)
Area
(pA*s)
Height
(pA)
Area
%
15.607BB0.03768.338114.496610.1097915.692BB0.037923.7040012.646590.25730
26.696BB0.03252.999091.708810.0394927.063BB0.038511.610096.029090.12603
38.018BV0.04561.064064.85292e-10.0140138.644BB0.11269162.004881206.6463699.45199
48.165VB0.04002.657371.292950.0349949.924BB0.04831.246295.13031e-10.01353
58.821BB0.056027.268407.945710.35904510.233BB0.04384.075171.997050.04424
69.302BB0.10367552.500981054.5590899.44269611.328BB0.05244.057061.459430.04404
713.140BB0.05222.072617.51371e-10.02250
813.614BB0.05371.370584.24300e-20.01488
914.565BB0.04902.349889.43809e-10.02551
  • Results from gas chromatograms of normal, partially deuterated, and perdeuterated additional odorants used herein. The percentage (Area %) of the total that constitutes the main species within each preparation is shown in bold. For acetophenone isotopologues, the purity of all preparations was >99.7%. The contribution of all contaminants was negligible as it ranged below 0.1%. Both ethanol isotopologues are 100% pure. For pentanol, the normal odorant was nearly pure (99.9%), while the deuterated isotopologue was highly pure at 99.5%, with two main, albeit low-level, contaminants: peak 1 at 0.16% and peak 2 at 0.33%. For octanol, the normal isotopologue was highly pure (99.4%), while the deuterated isotopologue is equally pure (99.5%). Although greater in number, the contribution of contaminants in the deuterated isotopologue is minor, except for the peak at 5.692 contributing 0.26% to the total. This peak is shared with the normal isotopologue at 5.607 and contributes 11% of the total while the major contaminating peak at 8.821 contributes 0.36%.